Size-selective formation of C78 fullerene from a three-dimensional polyyne precursor

Tobe Yoshito*, Rui Umeda, Motohiro Sonoda, Tomonari Wakabayashi

*Corresponding author for this work

研究成果: Article同行評審

17 引文 斯高帕斯(Scopus)


Multicyclic cagelike cyclophanes 2a and 2b containing cyclobutene rings have been prepared as precursors of three-dimensional polyynes C 78H18 (1a) and C78H12Cl6 (1b), respectively. Laser irradiation of 2a and 2b induced expulsion of the aromatic fragment, indane, to give the three-dimensional polyyne anions C 78H18- and C78H12Cl 6-, respectively. Whereas the former anion lost only four hydrogen atoms to form C78H14-, complete loss of all hydrogen and chlorine atoms was observed from the latter anion, to yield a C78- ion that has a fullerene structure which was proven by its characteristic fragmentation pattern.

頁(從 - 到)1603-1609
期刊Chemistry - A European Journal
出版狀態Published - 18 二月 2005

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