Ruthenium hydride-catalyzed addition of aldehydes to dienes leading to β,γ-unsaturated ketones

Sohei Omura, Takahide Fukuyama, Jiro Horiguchi, Yuji Murakami, Ilhyong Ryu*

*Corresponding author for this work

研究成果: Article同行評審

113 引文 斯高帕斯(Scopus)

摘要

An efficient cross-addition reaction of dienes with aldehydes was developped by using RuHCl(CO)(PPh3)3 as a catalyst to give a wide variety of β,γ-unsaturated ketones, where a π-allylruthenium species, derived from hydroruthenation of diene, may be involved as a key intermediate.

原文English
頁(從 - 到)14094-14095
頁數2
期刊Journal of the American Chemical Society
130
發行號43
DOIs
出版狀態Published - 29 十月 2008

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