Reductive bromine atom-transfer reaction

Shuhei Sumino, Akira Fusano, Ilhyong Ryu*

*Corresponding author for this work

研究成果: Article

22 引文 斯高帕斯(Scopus)

摘要

Atom-transfer radical (ATR) reactions of alkenes with R-X usually give products having new C-C and C-X bonds at the adjacent carbons. However, when the reaction was carried out under irradiation using a low-pressure Hg lamp, addition/reduction products were obtained in good yield. Hydrogen bromide, formed by H-abstraction of a bromine radical from alkenes, is likely to play a key role in the reductive ATR reaction.

原文English
頁(從 - 到)2826-2829
頁數4
期刊Organic Letters
15
發行號11
DOIs
出版狀態Published - 26 六月 2013

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