Reactions of metal-metal quintuple bonds with alkynes: [2+2+2] and [2+2] cycloadditions

Hong Zhang Chen*, Shih Cheng Liu, Chun Hsu Yen, Jen-Shiang K. Yu, Yun Jen Shieh, Ting Shen Kuo, Yi Chou Tsai

*Corresponding author for this work

研究成果: Article同行評審

56 引文 斯高帕斯(Scopus)

摘要

High five! The quintuply bonded molybdenum amidinate 1 reacts with two equivalents of 1-pentyne through a [2+2+2] cycloaddition reaction to give the first examples of the benzannulated product 2. The C4Mo2 rings exhibit aromatic character. Treatment of 1 with internal alkynes afforded the 2:1 and 1:1 [2+2] cycloadducts, which are mechanistically associated with the formation of 2.

原文English
頁(從 - 到)10342-10346
頁數5
期刊Angewandte Chemie - International Edition
51
發行號41
DOIs
出版狀態Published - 8 十月 2012

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