Photodissociation dynamics of vinyl chloride investigated with a pulsed slit-jet and time-resolved fourier-transform spectroscopy

Mohammed Bahou, Yuan-Pern Lee*

*Corresponding author for this work

研究成果: Article

10 引文 斯高帕斯(Scopus)

摘要

Following photodissociation of vinyl chloride seeded in a He supersonic jet at 193 nm, rotationally resolved infrared emission of HCl (v) are recorded to yield nascent rotational and vibrational distributions. Preliminary results show that the rotational distribution of HCl free from rotational quenching deviates slightly from Boltzmann-type distribution and agrees well with trajectory calculations; a portion of the low-J component observed previously in a flow system is attributed to quenching. The implications for photodissociation dynamics are discussed.

原文English
頁(從 - 到)1161-1164
頁數4
期刊Australian Journal of Chemistry
57
發行號12
DOIs
出版狀態Published - 1 十二月 2004

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