Palladium/Light induced radical alkenylation and allylation of alkyl iodides using alkenyl and allylic sulfones

Shuhei Sumino, Misae Uno, Hsin Ju Huang, Yen-Ku Wu, Ilhyong Ryu*

*Corresponding author for this work

研究成果: Article同行評審

26 引文 斯高帕斯(Scopus)

摘要

Alkenylation and allylation of alkyl iodides with alkenyl and allyl sulfones, respectively, took place under Pd/photoirradiation system. The initial alkyl radical, derived from a single electron transfer between Pd(0) and RI, underwent the title transformations. Pd(0) was regenerated through a reductive elimination of PhSO2PdI, which is formed by the combination of the sulfonyl radical and the palladium radical. The addition of water was effective, presumably by pushing the equilibrium through hydrolysis of PhSO2I.

原文English
頁(從 - 到)1078-1081
頁數4
期刊Organic Letters
20
發行號4
DOIs
出版狀態Published - 6 二月 2018

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