This research aims at understanding the heat transfer phenomenon in the Bi2Te3 nanoprism-assembled films. For obtaining the associated effective thermal conductivity, the effective-medium-approximation (EMA) models existing in literature were examined and properly modified for prediction and Monte-Carlo numerical experiments based on unstructured grids were performed for confirmation. Cross-plane and in-plane thermal conductivities were both explored. For model predictions, the characteristic grain size of the nanoprisms is defined as either the phonon mean free path purely due to the grain boundary scattering (i.e. excluding the intrinsic scattering) or the averaged hydraulic diameter. A combination of a non-dilute 2D EMA model with the triple bond percolation theory turns out to be the best model for predicting the in-plane thermal conductivity. On the other hand, the evaluation of the cross-plane thermal conductivity by treating the nanoprisms as thermal conductors connected in parallel is satisfactory. The investigation shows that in addition to porosity, the scattering at the grain boundaries plays a dominant role in reducing the heat transfer in the direction perpendicular to the boundaries; the in-plane thermal conductivity is therefore much smaller than the cross-plane one.
|頁（從 - 到）||536-543|
|期刊||International Journal of Heat and Mass Transfer|
|出版狀態||Published - 1 九月 2015|