Nonzero orbital moment in high coercivity ε-Fe2O 3 and low-temperature collapse of the magnetocrystalline anisotropy

Yuan-Chieh Tseng, Narcizo M. Souza-Neto, Daniel Haskel*, Martí Gich, Carlos Frontera, Anna Roig, Michel Van Veenendaal, Josep Nogués

*Corresponding author for this work

研究成果: Article同行評審

85 引文 斯高帕斯(Scopus)


The magnetic properties of ε-Fe2O3 nanoparticles are investigated by x-ray magnetic circular dichroism. Sum rules relating the orbital and spin moment in the Fe 3d band to the Fe L2,3 absorption cross sections show that the Fe orbital moment (morb) is considerably high, explaining the origin of the large coercivity of this material at room temperature. Moreover, at T∼110 K, the collapse of the coercivity (H c) and the magnetocrystalline anisotropy coincides with a strong reduction of the spin-orbit coupling evidenced by a drastic drop of m orb. The decrease in morb originates from changes in the electron transfer between Fe and O ions accompanied by significant modifications of some of the Fe-O bond distances. Similarly, the recovery of morb at lower temperatures mimics the behavior of the Fe-O bond lengths.

期刊Physical Review B - Condensed Matter and Materials Physics
出版狀態Published - 3 三月 2009

指紋 深入研究「Nonzero orbital moment in high coercivity ε-Fe<sub>2</sub>O <sub>3</sub> and low-temperature collapse of the magnetocrystalline anisotropy」主題。共同形成了獨特的指紋。