Mass-spectrometric determination of product branching probabilities for the NH2 + NO2 reaction at temperatures between 300 and 990 K

J. Park, Ming-Chang Lin*

*Corresponding author for this work

研究成果: Article

19 引文 斯高帕斯(Scopus)

摘要

The product branching ratio, α, for N2O formation in the reaction of NH2 with NO2 has been studied by mass spectrometry at seven temperatures between 300 and 990 K. The value of α was determined by kinetic modeling of the absolute yield of N2O. α was found to be 0.19 ± 0.02 without significant temperature dependence, assuming the total rate constant for NH2 + NO2 to be kt = 1.8 × 10-2 × T0.11 exp (+597/T) cm3/molecule · s in the temperature range studied. The effect of kt on α has been discussed.

原文English
頁(從 - 到)879-883
頁數5
期刊International Journal of Chemical Kinetics
28
發行號12
DOIs
出版狀態Published - 1 一月 1996

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