Low-pressure crystallization of sol-gel-derived PbZr 0.52 Ti 0.48 O 3 thin films at low temperature for low-voltage operation

Ding Yeong Wang*, Chao-Hsin Chien, Chun Yen Chang, Ching Chich Leu, Jung Yen Yang, Shiow Huey Chuang, Tiao Yuan Huang

*Corresponding author for this work

研究成果: Article同行評審

4 引文 斯高帕斯(Scopus)


The properties of sol-gel-derived 120-nm PbZr 0.52 Ti 0.48 O 3 thin films crystallized in low-pressure O 2 ambient at 500 °C have been investigated. It is found that PbZr 0.52 Ti 0.48 O 3 films crystallized in low-pressure oxygen ambient exhibit higher remanent polarization as well as a lower coercive field, compared to those annealed in O 2 atmosphere. The remanent polarization (i.e., 2P r ) for samples annealed in 60 mbar O 2 ambient is as high as 36 μC/cm 2 , and the coercive field (2E C ) is 99.9 kV/cm at an applied voltage of 2 V. The improvement of P-E hysteresis loops by low-pressure oxygen annealing is ascribed to less incorporation of oxygen and other residues in the resultant PbZr 0.52 Ti 0.48 O 3 films, since the reductions in the amount of these residual species are beneficial for the complete transformation of the perovskite structure. The reductions in oxygen content and amounts of other residues such as CO 2 and H 2 O are confirmed based on Auger depth profiles and thermal desorption spectra (TDS), respectively.

頁(從 - 到)2756-2758
期刊Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers
發行號5 A
出版狀態Published - 1 五月 2003

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