Hydroxymethylation of organic halides. Evaluation of a catalytic system involving a fluorous tin hydride reagent for radical carbonylation

Ilhyong Ryu*, Tatsuro Niguma, Satoshi Minakata, Mitsuo Komatsu, Sabine Hadida, Dennis P. Curran

*Corresponding author for this work

研究成果: Article同行評審

65 引文 斯高帕斯(Scopus)

摘要

Hydroxymethylation of organic halides 2 using a catalytic amount of fluorous tin hydride 1, CO, and NaBH 3 CN as a reducing agent, proceeded smoothly to give one-carbon homologated alcohols 5 in good yields. Three phase workup (water-dichloromethane-perfluorohexane) was conveniently performed for the separation of 1 and 5.

原文English
頁(從 - 到)7883-7886
頁數4
期刊Tetrahedron Letters
38
發行號45
DOIs
出版狀態Published - 10 十一月 1997

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