Femtosecond dynamics of retro Diels-Alder reactions: The concept of concertedness

Wei-Guang Diau*, Steven De Feyter, Ahmed H. Zewail

*Corresponding author for this work

研究成果: Article同行評審

71 引文 斯高帕斯(Scopus)

摘要

Using femtosecond-resolved mass spectrometry in a molecular beam, we report real-time studies of the retro Diels-Alder reactions of cyclohexene, norbornene and bicyclo[2,2,2]oct-2-ene. The experimental results and theoretical calculations elucidate the influence of conical intersections on ground-state reaction trajectories. We address the issue of concertedness on the actual time scale of the nuclear motion.

原文English
頁(從 - 到)134-144
頁數11
期刊Chemical Physics Letters
304
發行號3-4
DOIs
出版狀態Published - 30 四月 1999

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