Curiosity-driven research on acyl radicals

Ilhyong Ryu*

*Corresponding author for this work

研究成果: Article同行評審

2 引文 斯高帕斯(Scopus)

摘要

With a strong desire to develop radical carbonylation chemistry, we naturally focused our attention on the key reactive intermediate, the acyl radical. Acyl radicals have been regarded as nucleophilic radicals towards electron-poor alkenes, akin to vinyl radicals. However, deeming that acyl radicals may act as pseudo-carbonyl compounds, we observed acyl radicals to behave as electrophilic species, very unlike vinyl radicals. This essay is a personal account of the area of acyl radical chemistry.

原文English
頁(從 - 到)826-831
頁數6
期刊Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
74
發行號8
DOIs
出版狀態Published - 1 一月 2016

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