Cascade carbonylation methods leading to β-diketones and β-functionalized δ-diketones

Katsukiyo Miura, Mami Tojino, Naoki Fujisawa, Akira Hosomi*, Ilhyong Ryu

*Corresponding author for this work

研究成果: Article同行評審

29 引文 斯高帕斯(Scopus)

摘要

A radical combination: An intermolecular cascade reaction involving alkyl halides, CO, electron-deficient alkenes, and stannyl enolates proceeds smoothly by a radical chain pathway to give four-component coupling products in good to high yields (see scheme). A series of 1,5-diketones with a substituent at the 3-position was prepared by this method.

原文English
頁(從 - 到)2423-2425
頁數3
期刊Angewandte Chemie - International Edition
43
發行號18
DOIs
出版狀態Published - 26 四月 2004

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