Unusual rearrangement of tricyclo[6.3.0.01,4]undecan-5-one

Masaki Ue*, Hiroshi Tsukahara, Kazuya Kobiro, Kiyomi Kakiuchi, Tobe Yoshito, Yoshinobu Odaira

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

cis,trans-Tricyclo[6.3.0.01,4]undecan-5-one (2) rearranged under acidic conditions through unusual pathways to give cis,cis-tricyclo[6.3.0.01,5]undecan-4-one (3). The application to the α-methylene derivative of 2 afforded the angularly fused triquinane having an α-methylenecyclopentanone unit.

Original languageEnglish
Pages (from-to)3979-3980
Number of pages2
JournalTetrahedron Letters
Volume28
Issue number34
DOIs
StatePublished - 1 Jan 1987

Fingerprint Dive into the research topics of 'Unusual rearrangement of tricyclo[6.3.0.0<sup>1,4</sup>]undecan-5-one'. Together they form a unique fingerprint.

Cite this