Titanyl phthalocyanine (TiOPc) organic thin film transistors with highly π-π interaction

Huang-Ming Chen, Yung Hsing Chen, Bo Ruei Lin

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

The objective of this research is to obtain uniform vacuum-deposition triclinic phase II crystal of titanyl phthalocyanine (α-TiOPc) films from various TiOPc crystal forms. The crystal structure and morphology of vacuum-deposited TiOPc films can be manipulated by deposition rate and substrate temperature. Crystal structure was determined by X-ray diffraction (XRD). Thin film morphology was analyzed by scanning electron microscope (SEM). Highly ordered α-TiOPc film with an edge-on molecular orientation was deposited on octadecyltrichlorosilane (OTS) treated Si/SiO2 surface. All TiOPc crystal forms, such as amorphous, α and γ phases, provided me triclinic phase II crystal of TiOPc. The full width at half maximum (FWHM) of the peak at 7.5 degree in XRD spectra was 0.23, 0.27 and 0.29 for γ, α and amorphous powder when substrate temperature maintained at 180°C, respectively. The FWHM of me 7.5 degree peak can be achieved 0.22 deposited from all crystal forms at elevated temperature higher than 220°C The α-TiOPc deposition film exhibited an excellent p-type semiconducting behavior in air with dense packing structure due to the close π-π molecular packing. The devices, field-effect mobility range from 0.02 to 0.26 cm2/V s depending on various process parameters. The on/off current ratio (Ion/Ioff) is over 105. The TiOPc OTFTs will be applied as multi-parameter gas sensor in me near future.

Original languageEnglish
Title of host publicationOrganic Photovoltaics and Related Electronics - From Excitons to Devices
Pages127-131
Number of pages5
StatePublished - 1 Dec 2010
Event2010 MRS Spring Meeting - San Francisco, CA, United States
Duration: 5 Apr 20109 Apr 2010

Publication series

NameMaterials Research Society Symposium Proceedings
Volume1270
ISSN (Print)0272-9172

Conference

Conference2010 MRS Spring Meeting
CountryUnited States
CitySan Francisco, CA
Period5/04/109/04/10

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