Tin-free radical carbonylation: Thiol ester synthesis using alkyl allyl sulfone precursors, phenyl benzenethiosulfonate, and CO

Sangmo Kim; Sunggak Kim; Noboru Otsuka; Ilhyong Ryu

doi:10.1002/anie.200501606

Tin-free radical carbonylation: Thiol ester synthesis using alkyl allyl sulfone precursors, phenyl benzenethiosulfonate, and CO

Sangmo Kim, Sunggak Kim, Noboru Otsuka, Ilhyong Ryu

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

51 Scopus citations

Abstract

(Chemical Equation Presented) Remove contents from tin ... Thiol esters have been successfully synthesized through tin-free radical carbonylation (see scheme; V-40 = initiator). This approach can be further extended to sequential radical reactions involving cyclization, carbonylation, and trapping of acyl radicals by phenyl benzenethiosulfonate.

Original language	English
Pages (from-to)	6183-6186
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	38
DOIs	https://doi.org/10.1002/anie.200501606
State	Published - 26 Sep 2005

Keywords

Carbonylation
Radical reactions
Radicals
Synthetic methods

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abstract = "(Chemical Equation Presented) Remove contents from tin ... Thiol esters have been successfully synthesized through tin-free radical carbonylation (see scheme; V-40 = initiator). This approach can be further extended to sequential radical reactions involving cyclization, carbonylation, and trapping of acyl radicals by phenyl benzenethiosulfonate.",

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AU - Kim, Sangmo

AU - Kim, Sunggak

AU - Otsuka, Noboru

AU - Ryu, Ilhyong

PY - 2005/9/26

Y1 - 2005/9/26

N2 - (Chemical Equation Presented) Remove contents from tin ... Thiol esters have been successfully synthesized through tin-free radical carbonylation (see scheme; V-40 = initiator). This approach can be further extended to sequential radical reactions involving cyclization, carbonylation, and trapping of acyl radicals by phenyl benzenethiosulfonate.

AB - (Chemical Equation Presented) Remove contents from tin ... Thiol esters have been successfully synthesized through tin-free radical carbonylation (see scheme; V-40 = initiator). This approach can be further extended to sequential radical reactions involving cyclization, carbonylation, and trapping of acyl radicals by phenyl benzenethiosulfonate.

KW - Carbonylation

KW - Radical reactions

KW - Radicals

KW - Synthetic methods

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JO - Angewandte Chemie - International Edition

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SN - 1433-7851

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ER -

Tin-free radical carbonylation: Thiol ester synthesis using alkyl allyl sulfone precursors, phenyl benzenethiosulfonate, and CO

Abstract

Keywords

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