Theoretical studies of ZEKE spectroscopy and dynamics of high Rydberg states

Yi Hsieh Wang, Yoshiaki Teranishi, H. Mineo, S. D. Chao*, H. L. Selzle, H. J. Neusser, E. W. Schlag, S. H. Lin

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

A main purpose of this Letter is to show how to employ the inverse Born-Oppenheimer approximation as a basis set to study zero kinetic energy (ZEKE) spectroscopy and the autoionization dynamics of the ZEKE states. The calculations of channel couplings, quantum defects, intensity borrowing, vibrational and rotational autotionizations will be demonstrated by using a homonuclear diatomic molecule as an example.

Original languageEnglish
Pages (from-to)104-109
Number of pages6
JournalChemical Physics Letters
Volume486
Issue number4-6
DOIs
StatePublished - 12 Feb 2010

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