Synthesis, structure, and photophysical properties of dibenzo-[de, mn]naphthacenes

Tsun Cheng Wu*, Chia Hua Chen, Daijiro Hibi, Akihiro Shimizu, Yoshito Tobe, Yao Ting Wu

*Corresponding author for this work

Research output: Contribution to journalArticle

71 Scopus citations

Abstract

Zethrenes were synthesized by Pd-catalyzed cyclodimerization of 1-ethynyl-8-iodonaphthalenes. The structure of these cycloadducts was confirmed by X-ray crystal analysis. The bond lengths and bond alternation in the crystal structures reveal that the central two six-membered rings of the title compounds lack aromaticity.

Original languageEnglish
Pages (from-to)7059-7062
Number of pages4
JournalAngewandte Chemie - International Edition
Volume49
Issue number39
DOIs
StatePublished - 17 Sep 2010

Keywords

  • Alkynes
  • Aromaticity
  • Cycloaddition
  • Nickel palladium

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