Synthesis of perinaphthenones through rhodium-catalyzed dehydrative annulation of 1-naphthoic acids with alkynes

Takahide Fukuyama*, Taiki Sugimori, Shinji Maetani, Ilhyong Ryu

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

An efficient approach to the synthesis of perinaphthenones via the rhodium-catalyzed dehydrative annulation of 1-naphthoic acids with internal alkynes was developed. Norbornadiene can act as an acetylene equivalent to give unsubstituted perinaphthenones at the 2- and 3-positions via dehydrative annulation followed by a retro Diels-Alder reaction.

Original languageEnglish
Pages (from-to)7583-7587
Number of pages5
JournalOrganic and Biomolecular Chemistry
Volume16
Issue number41
DOIs
StatePublished - 5 Oct 2018

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