Synthesis of perfluorinated allylic compounds by radical allylation and their purification over fluorous reverse-phase silica

Ilhyong Ryu*, Sergio Kreimerman, Tatsuro Niguma, Satoshi Minakata, Mitsuo Komatsu, Zhiyong Luo, Dennis P. Curran

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

39 Scopus citations

Abstract

A simple free-radical method for the preparation of a variety of perfluorinated allylic compounds has been developed starting from perfluoroalkyl iodides and allyltins. Allyltributyltin, methallyltributyltin and crotyltributyltin all proved to be useful for the transformation. The desired perfluorinated allylic compound was conveniently isolated from the crude mixture by solid-phase extraction with fluorous reverse-phase silica (FRPS).

Original languageEnglish
Pages (from-to)947-950
Number of pages4
JournalTetrahedron Letters
Volume42
Issue number5
DOIs
StatePublished - 29 Jan 2001

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