Synthesis of Cu 2 O nanoparticle films at room temperature for solar water splitting

Yan Gu Lin*, Yu Kuei Hsu, Yu Chang Lin, Yu Hsueh Chang, San-Yuan Chen, Ying Chu Chen

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

14 Scopus citations

Abstract

A Cu 2 O nanoparticle film using ZnO nanorods as a sacrificial scaffold was fabricated near 23 °C, for applications in photoelectrochemical (PEC) water splitting. Three chemical solutions were utilized to convert ZnO nanorods to a Cu 2 O nanoparticle film - solutions of CuCl 2 and NaOH, NaBH 4 and NaOH, respectively. The structural evolution from ZnO through Cu(OH) 2 and metallic Cu to Cu 2 O phase was analyzed at each stage with X-ray diffraction and X-ray absorption spectra. The energy bandgap was deduced from IPCE; the concentration of carriers and flat-band of a Cu 2 O nanoparticle film were obtained from a Mott-Schottky plot. Significantly, the Cu 2 O nanoparticle film exhibited a useful PEC response to water oxidation. This nanostructure synthesized with no energy requirement can not only illustrate a great prospect for solar generation of hydrogen but also offer a blueprint for the future design of photocatalysts.

Original languageEnglish
Pages (from-to)76-80
Number of pages5
JournalJournal of Colloid And Interface Science
Volume471
DOIs
StatePublished - 1 Jun 2016

Keywords

  • Copper(I) oxide
  • Nanoparticles
  • Photoelectrochemical
  • Zinc oxide

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