Synthesis of carbamoylacetates from α-iodoacetate, CO, and amines under Pd/light combined conditions

Shuhei Sumino, Akira Fusano, Takahide Fukuyama, Ilhyong Ryu*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

We developed a novel synthetic method of carbamoylacetates from -iodoacetate, carbon monoxide, and amines under photoirradiation conditions in the presence of a Pd catalyst. This reaction likely proceeds via interplay of radical and organopalladium species.

Original languageEnglish
Pages (from-to)1331-1334
Number of pages4
JournalSynlett
Volume23
Issue number9
DOIs
StatePublished - 16 May 2012

Keywords

  • carbamoylacetates
  • carbonylation
  • palladium
  • photo reaction
  • radical reaction

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