Synthesis and linear and nonlinear optical properties of metal-terminated bis(dioxaborine) polymethines

Hsin-Chieh Lin; Hyeongeu Kim; Stephen Barlow; Joel M. Hales; Joseph W. Perry; Seth R. Marder

doi:10.1039/c0cc02003f

Synthesis and linear and nonlinear optical properties of metal-terminated bis(dioxaborine) polymethines

Hsin-Chieh Lin^*, Hyeongeu Kim, Stephen Barlow, Joel M. Hales, Joseph W. Perry, Seth R. Marder

^*Corresponding author for this work

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Rh^III and Ir^III can be complexed to bipyridine groups attached to the termini of bis(dioxaborine)-capped heptamethines; these chromophores exhibit large third-order polarisabilities at 1.55 μm, while retaining good film-forming properties and linear optical transparency in the near infrared.

Original language	English
Pages (from-to)	782-784
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	2
DOIs	https://doi.org/10.1039/c0cc02003f
State	Published - 14 Jan 2011

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title = "Synthesis and linear and nonlinear optical properties of metal-terminated bis(dioxaborine) polymethines",

abstract = "RhIII and IrIII can be complexed to bipyridine groups attached to the termini of bis(dioxaborine)-capped heptamethines; these chromophores exhibit large third-order polarisabilities at 1.55 μm, while retaining good film-forming properties and linear optical transparency in the near infrared.",

author = "Hsin-Chieh Lin and Hyeongeu Kim and Stephen Barlow and Hales, {Joel M.} and Perry, {Joseph W.} and Marder, {Seth R.}",

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AU - Hales, Joel M.

AU - Perry, Joseph W.

AU - Marder, Seth R.

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AB - RhIII and IrIII can be complexed to bipyridine groups attached to the termini of bis(dioxaborine)-capped heptamethines; these chromophores exhibit large third-order polarisabilities at 1.55 μm, while retaining good film-forming properties and linear optical transparency in the near infrared.

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