Synthesis and characterization of poly(pyrrolyl methine)

Wei Yan*, An Kuo Li, Chain-Shu Hsu, Zhi Cheng Zhang, Mei Xiang Wan

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

A novel small band-gap conjugated polymer - poly[(3-acetylpyrrole-2,5-diyl)(4-dimethylaminobenzyliene)(3- acetylpyrrolequinodimethane-2,5-diyl)] (PAPDMABE) - and its precursor were synthesized by a simple method and characterized by 1H-NMR, FT-IR, TGA and UV-VIS. The polymer can be dissolved in strong polar solvents such as DMSO, DMF or NMP. The band-gap energy of PAPDMABE was found to be 0.95 eV. The conductivity of doped products with iodine falls in the range of a semiconductor.

Original languageEnglish
Pages (from-to)499-502
Number of pages4
JournalChinese Journal of Polymer Science (English Edition)
Volume19
Issue number5
StatePublished - 1 Sep 2001

Keywords

  • Conducting polymer
  • Poly(pyrrolyl methine)
  • Small band-gap

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