Synthesis and characterization of polyimide-silica nanocomposites using novel fluorine-modified silica nanoparticles

Te Cheng Mo, Hong Wen Wang*, San-Yuan Chen, Rui Xuan Dong, Chien Hung Kuo, Yun Chieh Yeh

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

11 Scopus citations


Polyimide-silica nanocomposites were synthesized with 4,4′- oxydianiline, 4,4′-(4,4′-isopropylidenediphenoxy)bis(phthalic anhydride), and fluorine-modified silica nanoparticles. Fluorinated precursors such as 4″,4‴-(hexafluoroisopropylidene)bis(4-phenoxyaniline) (6FBPA) and 4,4′-(hexafluoroisopropylindene)diphenol (BISAF) were employed to modify the surface of the silica nanoparticles. The microstructures and thermal, mechanical, and dielectric properties of the polyimide-silica nanocomposites were investigated. An improvement in the thermal stability and storage modulus of the polyimide nanocomposites due to the addition of the modified silica nanoparticles was observed. The microstructures of the polyimide-silica nanocomposites containing 6FBPA-modified silica exhibited more uniformity than those of the nanocomposites contain ing BISAF-modified silica. The dielectric constants of the polyimide were considerably reduced by the incorporation of pristine silica or 6FBPA-modified silica but not BISAF-modified silica. The addition of a modifier with higher fluorine contents did not ensure a lower dielectric constant. The uniformity of the silica distribution, manipulated by the reactivity of the modifier, played an important role in the reduction of the dielectric constant. Using 6FBPA-modified silica nanoparticles demonstrated an effective way of synthesizing low-dielectric-constant polyimide-silica nanocomposites.

Original languageEnglish
Pages (from-to)882-890
Number of pages9
JournalJournal of Applied Polymer Science
Issue number2
StatePublished - 15 Apr 2007


  • Composites
  • Dielectric properties
  • Nanocomposites
  • Polyimides
  • Silicas

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