Synthesis and association behavior of [4.4.4.4.4.4]metacyclophanedodecayne derivatives with interior binding groups

Yoshito Tobe; Naoto Utsumi; Atsushi Nagano; Koichiro Naemura

doi:10.1002/(SICI)1521-3773(19980518)37:9<1285::AID-ANIE1285>3.0.CO;2-B

Synthesis and association behavior of [4.4.4.4.4.4]metacyclophanedodecayne derivatives with interior binding groups

Yoshito Tobe^*, Naoto Utsumi, Atsushi Nagano, Koichiro Naemura

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

124 Scopus citations

Abstract

Intriguing association behavior in solution is exhibited by the rigid macrocycle 1. For instance, it reacts with organic cations to give ternary complexes of the composition (1 · cation) · 1, and with analogous macrocycles without cyano groups it forms heteroaggregates. R = CO₂C₈H₁₇.

Original language	English
Pages (from-to)	1285-1287
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	37
Issue number	9
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19980518)37:9<1285::AID-ANIE1285>3.0.CO;2-B
State	Published - 18 May 1998

Keywords

Carbocations
Cyclophanes
Host-guest chemistry
Macrocycles
Molecular recognition

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10.1002/(SICI)1521-3773(19980518)37:9<1285::AID-ANIE1285>3.0.CO;2-B

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title = "Synthesis and association behavior of [4.4.4.4.4.4]metacyclophanedodecayne derivatives with interior binding groups",

abstract = "Intriguing association behavior in solution is exhibited by the rigid macrocycle 1. For instance, it reacts with organic cations to give ternary complexes of the composition (1 · cation) · 1, and with analogous macrocycles without cyano groups it forms heteroaggregates. R = CO2C8H17.",

keywords = "Carbocations, Cyclophanes, Host-guest chemistry, Macrocycles, Molecular recognition",

author = "Yoshito Tobe and Naoto Utsumi and Atsushi Nagano and Koichiro Naemura",

year = "1998",

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AU - Tobe, Yoshito

AU - Utsumi, Naoto

AU - Nagano, Atsushi

AU - Naemura, Koichiro

PY - 1998/5/18

Y1 - 1998/5/18

N2 - Intriguing association behavior in solution is exhibited by the rigid macrocycle 1. For instance, it reacts with organic cations to give ternary complexes of the composition (1 · cation) · 1, and with analogous macrocycles without cyano groups it forms heteroaggregates. R = CO2C8H17.

AB - Intriguing association behavior in solution is exhibited by the rigid macrocycle 1. For instance, it reacts with organic cations to give ternary complexes of the composition (1 · cation) · 1, and with analogous macrocycles without cyano groups it forms heteroaggregates. R = CO2C8H17.

KW - Carbocations

KW - Cyclophanes

KW - Host-guest chemistry

KW - Macrocycles

KW - Molecular recognition

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 9

ER -

Synthesis and association behavior of [4.4.4.4.4.4]metacyclophanedodecayne derivatives with interior binding groups

Abstract

Keywords

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