Syntheses and Characterization of Organoimido Complexes of Niobium(V); Potential CVD Precursors

Hsin-Tien Chiu*, Jyh Cherng Lin, Shiow Huey Chuang, Gene Hsiang Lee, Shie Ming Peng

*Corresponding author for this work

Research output: Contribution to journalArticle

13 Scopus citations

Abstract

New niobium imido complexes (RN)Nb(NEt2)3 (R = Prn, Pri and But), potential precursors to grow niobium containing thin films by chemical vapor deposition (CVD), were prepared by reacting the corresponding (RN)NbCl3Py2 complexes (R = Prn, Pri and But; py = pyridine) with LiNEt2 in hydrocarbon solvents. The structures of (RN)NbCl3py2 (R = Pri and But), determined by X-ray crystallography, are mononuclear with distorted octahedral geometries. For each complex, three chloride ligands are cis to the imido ligand and occupy meridional positions. One of two py ligands is cis to and the other is trans to the imido ligand. For (PriN)NbCl3py2, the Nb=NPri bond distance (Å) is 1.733(3) and the 〈Nb=N-Pri angle (°) is 178.0(3). Crystal data: monoclinic, space group P21/n, a = 8.805(2), b = 14.930(4), c = 13.407(3) Å, ß = 93.37(2)°, V = 1759.5(7) Å3, Z = 4, DC = 1.565 g cm-3. For (ButN)NbCl3py2, the Nb=NBut bond distance (Å) is 1.734(4)and the ZNb=N-But angle (°) is 174.8(4). Crystal data: monoclinic, space group P21/c, a = 9.609(1), b = 13.591(6), c = 14.615(2) Å, ß = 90.05(1)°, V = 1908.5(9) Å3, Z = 4, Dc = 1.492 g cm -3.

Original languageEnglish
Pages (from-to)355-360
Number of pages6
JournalJournal of the Chinese Chemical Society
Volume45
Issue number3
DOIs
StatePublished - 1 Jan 1998

Keywords

  • CVD precursors
  • Niobium complex
  • Organoimido ligands

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