Supramolecular Metallacycles and Their Binding of Fullerenes

Christian R. Göb, Andreas Ehnbom, Lisa Sturm, Yoshito Tobe, Iris M. Oppel*

*Corresponding author for this work

Research output: Contribution to journalArticle

1 Scopus citations

Abstract

The synthesis of a new triaminoguanidinium-based ligand with three tris-chelating [NNO]-binding pockets and C3 symmetry is described. The reaction of tris-(2-pyridinylene-N-oxide)triaminoguanidinium salts with zinc(II) formate leads to the formation of cyclic supramolecular coordination compounds which in solution bind fullerenes in their spherical cavities. The rapid encapsulation of C60 can be observed by NMR spectroscopy and single-crystal X-ray diffraction and is verified using computation.

Original languageEnglish
Pages (from-to)3609-3613
Number of pages5
JournalChemistry - A European Journal
Volume26
Issue number16
DOIs
StatePublished - 18 Mar 2020

Keywords

  • cage compounds
  • density functional calculations
  • fullerenes
  • host–guest systems
  • self-assembly

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