Styrene/maleimide copolymer with stable second-order optical nonlinearity

Po Hou Sung*, Chung Yung Chen, Shin Yu Wu, Jung Y. Huang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

21 Scopus citations

Abstract

Radical copolymerization of N-(azo dye) maleimide or N-(substituted phenyl) maleimide and styrene were carried out using 2,2′-azobis-isobutyronitrile as an initiator in THF at 60°C. These copolymers exhibit high solubility in most of the organic solvents and excellent thermal stability up to 280°C under nitrogen atmosphere. The copolymer films which were heated at 200-240°C under high corona field exhibit dx1 = 3-5 pm/V, in the Maker-fringe measurement. Experimental results also showed that the copolymer with azo dye as chromophore did not decay in second harmonic response even at 130°C.

Original languageEnglish
Pages (from-to)2189-2194
Number of pages6
JournalJournal of Polymer Science, Part A: Polymer Chemistry
Volume34
Issue number11
DOIs
StatePublished - 1 Jan 1996

Keywords

  • Copolymer
  • Maleimide
  • NLO
  • Styrene
  • Thermal stability

Fingerprint Dive into the research topics of 'Styrene/maleimide copolymer with stable second-order optical nonlinearity'. Together they form a unique fingerprint.

Cite this