Stannylformylation of 1,6-Dienes Accompanied by Five-Membered Radical Ring Closure

Ilhyong Ryu*, Akio Kurihara, Hideo Muraoka, Shinji Tsunoi, Nobuaki Kambe, Noboru Sonoda

*Corresponding author for this work

Research output: Contribution to journalArticle

28 Scopus citations

Abstract

Treatment of 1,6-dienes with tin hydride and AIBN (catalytic) under CO pressure leads to fivemembered carbocycles flanked by stannylmethyl and formylmethyl groups at the adjacent carbons by way of a stannyl radical addition–cyclization–carbonylation sequence.

Original languageEnglish
Pages (from-to)7570-7571
Number of pages2
JournalJournal of Organic Chemistry
Volume59
Issue number25
DOIs
StatePublished - 1 Dec 1994

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