Spectroscopic studies of small radicals (CH3S)

Yuan-Pern Lee*

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

1 Scopus citations

Abstract

The CH3S radical was formed from reaction of dimethyl disulfide (CH3SSCH3) with microwave discharged O2 in a flow tube. The Ā 2A′ ← X̄ 2A″ fluorescence excitation spectrum was observed in the wavelength region 615 - 692 nm. The origin was located at 14,542 cm-1; the vibrational frequency for the S-O stretching of the Ā state was 859 cm-1. Dispersed fluorescence was observed in the 680 - 850 nm region. The main progressions gave vibrational frequencies of 1066 cm-15″, S-O stretching), 704 cm-17″, C-S stretching), and 1464 cm-14″, CH3-deformation). The results agree with ab initio calculations. Infrared absorption lines of the CH3S radical were observed after UV photolysis of a CH3SH/Ar (1/500) matrix at 12 K. The results yielded ν1 (C-H stretching) = 2948.6, ν2 (CH3-umbrella) = 1315.1, ν3 (C-S stretching) = 719.4, ν4 ≈ 2873, and 2ν6 (CH3 rocking) = 1154 cm-1.

Original languageEnglish
Title of host publicationProceedings of SPIE - The International Society for Optical Engineering
PublisherPubl by Int Soc for Optical Engineering
Pages44-46
Number of pages3
ISBN (Print)0819410853
DOIs
StatePublished - 1 Dec 1993

Publication series

NameProceedings of SPIE - The International Society for Optical Engineering
Volume1858
ISSN (Print)0277-786X

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