Solvent‐Mediated Iodine Intercalation of a High‐Tc Oxide Superconductor Bi2Sn1.8Ca1.2CU2Ox

T. N. Guo*, Teng-Ming Chen

*Corresponding author for this work

Research output: Contribution to journalArticle

2 Scopus citations

Abstract

The benzene‐mediated iodine intercalation into the pseudo‐layered superconductor Bi2Sr1.8Ca1.2Cu2Ox (2212) is an efficient way to prepare an intercalate with nominal composition IBi2Sr1.8Ca1.2Cu2Ox. Expansion by 22 percent along the crystallographic c‐axis was observed but both a‐and b‐axes of the intercalates remained unchanged. The superconducting temperature (Tc) of 2212 phase decreased 10 K upon iodine intercalation. We report the First solvent‐mediated intercalation reaction and preliminary characterizations of a presumably stage‐1 phase IBi2Sr1.8Ca1.2Cu2Ox.

Original languageEnglish
Pages (from-to)149-152
Number of pages4
JournalJournal of the Chinese Chemical Society
Volume40
Issue number2
DOIs
StatePublished - 1 Jan 1993

Keywords

  • Bismuth superconductor
  • Iodine‐intercalation
  • Magnetic susceptibility
  • XRD

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