Silylcarbonylation of 1,5-dienes accompanied by acyl radical cyclization

Ilhyong Ryu*, Kiyoto Nagahara, Akio Kurihara, Mitsuo Komatsu, Noboru Sonoda

*Corresponding author for this work

Research output: Contribution to journalArticle

9 Scopus citations

Abstract

2-(Silylmethyl)cyclopentanones are prepared from 1,5-dienes, carbon monoxide, and tris(trimethylsilyl)silane (TTMSS) under AIBN initiated free radical reaction conditions.

Original languageEnglish
Pages (from-to)105-107
Number of pages3
JournalJournal of Organometallic Chemistry
Volume548
Issue number1
DOIs
StatePublished - 5 Dec 1997

Keywords

  • 1,5-Dienes
  • Carbon monoxide
  • Cyclization
  • Radical
  • Silicon hydride
  • Silylcarbonylation

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