Selenium‐Catalyzed Synthesis of S‐Alkyl Thiocarbamates from Amines, Carbon Monoxide, Sulfur, and Alkyl Halides

Noboru Sonoda*, Takumi Mizuno, Sinkichi Murakami, Kiyoshi Kondo, Akiya Ogawa, Ilhyong Ryu, Nobuaki Kambe

*Corresponding author for this work

Research output: Contribution to journalArticle

34 Scopus citations

Abstract

1 atm CO, 30°C, and 10 mol% selenium—these are the conditions under which the S‐alkyl thiocarbamates 1 were obtained in 41–100% yield according to Equation (a). The presumed intermediates are selenocarbamates, carbonyl selenide, and carbonyl sulfide. R1,R2 = Et, nPr, nPr, nBu, Ph, H; R3 = Me, Et, PhCH2, 4‐ClC6H4CH2. (Figure Presented.)

Original languageEnglish
Pages (from-to)452-453
Number of pages2
JournalAngewandte Chemie International Edition in English
Volume28
Issue number4
DOIs
StatePublished - 1 Jan 1989

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