Selective [2+1] aziridination of conjugated dienes with a nitridomanganese complex: A new route to alkenylaziridines

M. Nishimura; S. Minakata; S. Thongchant; Ilhyong Ryu; M. Komatsu

doi:10.1016/S0040-4039(00)01219-3

Selective [2+1] aziridination of conjugated dienes with a nitridomanganese complex: A new route to alkenylaziridines

M. Nishimura, S. Minakata, S. Thongchant, Ilhyong Ryu, M. Komatsu^*

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

Conjugated dienes were successfully aziridinated using a nitridomanganese complex as a nitrogen source. The reaction proceeded selectively and in good yield via [2+1] addition to give alkenylaziridines, with no evidence for the formation of any [4+1] addition products. The first asymmetric version of the reaction was revealed in the aziridination of diene 5 with chiral complex 1. (C) 2000 Elsevier Science Ltd.

Original language	English
Pages (from-to)	7089-7092
Number of pages	4
Journal	Tetrahedron Letters
Volume	41
Issue number	36
DOIs	https://doi.org/10.1016/S0040-4039(00)01219-3
State	Published - 2 Sep 2000

Keywords

Alkenylaziridine
Aziridination
Conjugated diene
Nitridomanganese complex

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title = "Selective [2+1] aziridination of conjugated dienes with a nitridomanganese complex: A new route to alkenylaziridines",

abstract = "Conjugated dienes were successfully aziridinated using a nitridomanganese complex as a nitrogen source. The reaction proceeded selectively and in good yield via [2+1] addition to give alkenylaziridines, with no evidence for the formation of any [4+1] addition products. The first asymmetric version of the reaction was revealed in the aziridination of diene 5 with chiral complex 1. (C) 2000 Elsevier Science Ltd.",

keywords = "Alkenylaziridine, Aziridination, Conjugated diene, Nitridomanganese complex",

author = "M. Nishimura and S. Minakata and S. Thongchant and Ilhyong Ryu and M. Komatsu",

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doi = "10.1016/S0040-4039(00)01219-3",

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T1 - Selective [2+1] aziridination of conjugated dienes with a nitridomanganese complex

T2 - A new route to alkenylaziridines

AU - Nishimura, M.

AU - Minakata, S.

AU - Thongchant, S.

AU - Ryu, Ilhyong

AU - Komatsu, M.

PY - 2000/9/2

Y1 - 2000/9/2

N2 - Conjugated dienes were successfully aziridinated using a nitridomanganese complex as a nitrogen source. The reaction proceeded selectively and in good yield via [2+1] addition to give alkenylaziridines, with no evidence for the formation of any [4+1] addition products. The first asymmetric version of the reaction was revealed in the aziridination of diene 5 with chiral complex 1. (C) 2000 Elsevier Science Ltd.

AB - Conjugated dienes were successfully aziridinated using a nitridomanganese complex as a nitrogen source. The reaction proceeded selectively and in good yield via [2+1] addition to give alkenylaziridines, with no evidence for the formation of any [4+1] addition products. The first asymmetric version of the reaction was revealed in the aziridination of diene 5 with chiral complex 1. (C) 2000 Elsevier Science Ltd.

KW - Alkenylaziridine

KW - Aziridination

KW - Conjugated diene

KW - Nitridomanganese complex

UR - http://www.scopus.com/inward/record.url?scp=0034596425&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)01219-3

DO - 10.1016/S0040-4039(00)01219-3

M3 - Article

AN - SCOPUS:0034596425

VL - 41

SP - 7089

EP - 7092

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 36

ER -

Selective [2+1] aziridination of conjugated dienes with a nitridomanganese complex: A new route to alkenylaziridines

Abstract

Keywords

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