Ruthenium hydride-catalyzed addition of aldehydes to dienes leading to β,γ-unsaturated ketones

Sohei Omura; Takahide Fukuyama; Jiro Horiguchi; Yuji Murakami; Ilhyong Ryu

doi:10.1021/ja806929y

Ruthenium hydride-catalyzed addition of aldehydes to dienes leading to β,γ-unsaturated ketones

Sohei Omura, Takahide Fukuyama, Jiro Horiguchi, Yuji Murakami, Ilhyong Ryu^*

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

114 Scopus citations

Abstract

An efficient cross-addition reaction of dienes with aldehydes was developped by using RuHCl(CO)(PPh₃)₃ as a catalyst to give a wide variety of β,γ-unsaturated ketones, where a π-allylruthenium species, derived from hydroruthenation of diene, may be involved as a key intermediate.

Original language	English
Pages (from-to)	14094-14095
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	43
DOIs	https://doi.org/10.1021/ja806929y
State	Published - 29 Oct 2008

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title = "Ruthenium hydride-catalyzed addition of aldehydes to dienes leading to β,γ-unsaturated ketones",

abstract = "An efficient cross-addition reaction of dienes with aldehydes was developped by using RuHCl(CO)(PPh3)3 as a catalyst to give a wide variety of β,γ-unsaturated ketones, where a π-allylruthenium species, derived from hydroruthenation of diene, may be involved as a key intermediate.",

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AU - Omura, Sohei

AU - Fukuyama, Takahide

AU - Horiguchi, Jiro

AU - Murakami, Yuji

AU - Ryu, Ilhyong

PY - 2008/10/29

Y1 - 2008/10/29

N2 - An efficient cross-addition reaction of dienes with aldehydes was developped by using RuHCl(CO)(PPh3)3 as a catalyst to give a wide variety of β,γ-unsaturated ketones, where a π-allylruthenium species, derived from hydroruthenation of diene, may be involved as a key intermediate.

AB - An efficient cross-addition reaction of dienes with aldehydes was developped by using RuHCl(CO)(PPh3)3 as a catalyst to give a wide variety of β,γ-unsaturated ketones, where a π-allylruthenium species, derived from hydroruthenation of diene, may be involved as a key intermediate.

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Ruthenium hydride-catalyzed addition of aldehydes to dienes leading to β,γ-unsaturated ketones

Abstract

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