Remarkable effects of chirality on deslipping reactions of diastereomeric rotaxanes and relevant mechanism involving pre-equilibrium

Keiji Hirose*, Yamato Nakamura, Tobe Yoshito

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

The first clear differentiation on deslipping rates affected by the difference in the diastereomeric stereocenters of rotaxanes up to 8.4 times and unexpectedly large steric kinetic isotope effect on the deslipping reaction.

Original languageEnglish
Pages (from-to)145-147
Number of pages3
JournalOrganic Letters
Volume11
Issue number1
DOIs
StatePublished - 1 Jan 2009

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