Reductive bromine atom-transfer reaction

Shuhei Sumino, Akira Fusano, Ilhyong Ryu*

*Corresponding author for this work

Research output: Contribution to journalArticle

22 Scopus citations

Abstract

Atom-transfer radical (ATR) reactions of alkenes with R-X usually give products having new C-C and C-X bonds at the adjacent carbons. However, when the reaction was carried out under irradiation using a low-pressure Hg lamp, addition/reduction products were obtained in good yield. Hydrogen bromide, formed by H-abstraction of a bromine radical from alkenes, is likely to play a key role in the reductive ATR reaction.

Original languageEnglish
Pages (from-to)2826-2829
Number of pages4
JournalOrganic Letters
Volume15
Issue number11
DOIs
StatePublished - 26 Jun 2013

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