Preparation of homochiral phenolic crown ethers containing para-substituted phenol moiety and chiral subunits derived from (S)-1-phenylethane-1,2-diol: Their chiral recognition behaviour in complexation with neutral amines

Koichiro Naemura*, Yasushi Nishikawa, Junichi Fuji, Keiji Hirose, Tobe Yoshito

*Corresponding author for this work

Research output: Contribution to journalArticle

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Abstract

Crown ethers 1-6 containing two chiral subunits derived from (S)-1-phenylethane-1, 2-diol and a phenol moiety bearing an intra-annular OH group and an additional para-substituent have been prepared in enantiomerically pure forms and their enantiomer recognition behaviour in complexation with neutral amines has been examined by the 1H n.m.r. spectroscopic method.

Original languageEnglish
Pages (from-to)873-882
Number of pages10
JournalTetrahedron Asymmetry
Volume8
Issue number6
DOIs
StatePublished - 27 Mar 1997

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