Photoredox-Catalyzed Hydrodifluoroalkylation of Alkenes Using Difluorohaloalkyl Compounds and a Hantzsch Ester

Shuhei Sumino, Misae Uno, Takahide Fukuyama, Ilhyong Ryu*, Makoto Matsuura, Akinori Yamamoto, Yosuke Kishikawa

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

52 Scopus citations

Abstract

Photoredox-catalyzed hydrodifluoroalkylation of alkenes proceeded smoothly in the presence of a Hantzsch ester as a hydrogen source under visible light irradiation. The reaction was also applicable to the hydrodifluoroalkylation of alkynes, and a continuous photo flow reaction was also successful.

Original languageEnglish
Pages (from-to)5469-5474
Number of pages6
JournalJournal of Organic Chemistry
Volume82
Issue number10
DOIs
StatePublished - 19 May 2017

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