Palladium-Catalyzed Cascade Arylation of Vinylogous Esters Enabled by Tris(1-adamantyl)phosphine

Yi-Chi Yang, Yi Ching Lin, Yen-Ku Wu*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

Described is a method for the transformation of a cyclic vinylogous ester to the corresponding polyarylated product. We found a catalytic system comprising palladium diacetate and tris(1-adamantyl)phosphine is quite effective in promoting a set of controlled cascade arylations. As a result, a range of novel (hetero)aryl-containing scaffolds was synthesized with a high level of efficiency.
Original languageEnglish
Pages (from-to)9286-9290
Number of pages5
JournalOrganic Letters
Volume21
Issue number23
DOIs
StatePublished - 6 Dec 2019

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