One-step preparation of coaxial CdS-ZnS and Cd1-xZn xS-ZnS nanowires

Yung-Jung Hsu*, Shih Yuan Lu, Yi Feng Lin

*Corresponding author for this work

Research output: Contribution to journalArticle

106 Scopus citations

Abstract

Preparation of coaxial (core-shell) CdS-ZnS and Cd1-xZn xS-ZnS nanowires has been achieved via a one-step metal-organic chemical vapor deposition (MOCVD) process with co-fed single-source precursors of CdS and ZnS. Single-source precursors of CdS and ZnS of sufficient reactivity difference were prepared and paired up to form coaxial nanostructures in a one-step process. The sequential growth of ZnS on CdS nanowires was also conducted to demonstrate the necessity and advantages of the precursor co-feeding practice for the formation of well-defined coaxial nanostructures. The coaxial naaostructure was characterized and confirmed by high-resolution transmission electron microscopy and corresponding energy dispersive X-ray spectrometry analyses. The photoluminescence efficiencies of the resulting coaxial CdS-ZnS and Cdi1-xZnxS-ZnS nanowires were significantly enhanced compared to those of the plain CdS and plain Cd 1-xZnxS nanowires, respectively, owing to the effective passivation of the surface electronic states of the core materials by the ZnS shell.

Original languageEnglish
Pages (from-to)1350-1357
Number of pages8
JournalAdvanced Functional Materials
Volume15
Issue number8
DOIs
StatePublished - 1 Aug 2005

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