On the structural change of some TCNB complexes in the excited singlet state

Hiroshi Masuhara*, N. Mataga

*Corresponding author for this work

Research output: Contribution to journalArticle

14 Scopus citations

Abstract

The absorption spectra of the TCNB-toluene complex in the fluorescent state at 4.2°K were observed. On the basis of the results of excited singlet-singlet absorption spectra of some TCNB complexes at various temperatures, available fluorescence spectral data were re-interpreted. Instead of the model of so-called structural change, an alternative explanation in terms of the triple complex (D2+A-) in the excited state is proposed.

Original languageEnglish
Pages (from-to)305-308
Number of pages4
JournalChemical Physics Letters
Volume22
Issue number2
DOIs
StatePublished - 1 Oct 1973

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