Novel chiral recognition beyond the limitation due to the law of mass action: Highly enantioselective chiral sensing based on non-linear response in phase transition events

Keiji Hirose*, Yuka Yachi, Tobe Yoshito

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

Based on non-linear response in phase transition events exhibiting a sharp transmittance change, an intelligent chiral sensor capable of chirality amplification in aqueous media was designed and constructed as poly(N-isopropylacrylamide) having chiral pseudo-18-crown-6. Both sensitivity and selectivity of the sensor surmount the limitation due to the law of mass action.

Original languageEnglish
Pages (from-to)6617-6619
Number of pages3
JournalChemical Communications
Volume47
Issue number23
DOIs
StatePublished - 21 Jun 2011

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