Novel acid-catalysed rearrangement of [4.3.2]- and [5.3.2]-propellanones

Kiyomi Kakiuchi*, Yukinori Hato, Tobe Yoshito, Yoshinobu Odaira

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

The reactions of the [4.3.2]- and [5.3.2]-propellanones (1) and (2) with toluene-p-sulphonic acid in acetic acid or sulphuric acid in aqueous tetrahydrofuran led to the tricyclo[4.3.2.01,5]undecane derivatives (5) or (6) and the tricyclo[5.3.2.01,6]dodecane derivatives (7) or (8), respectively, by a novel rearrangement.

Original languageEnglish
Pages (from-to)6-7
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number1
DOIs
StatePublished - 1 Jan 1982

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