Mo(CO)6-mediated synthesis of calix[4]arenes carrying β-hydroxy ketones or α,β-unsaturated-β-amino ketones

Annamalai Senthilvelan; Ming Tsung Tsai; Kai Chi Chang; Wen-Sheng Chung

doi:10.1016/j.tetlet.2006.10.082

Mo(CO)6-mediated synthesis of calix[4]arenes carrying β-hydroxy ketones or α,β-unsaturated-β-amino ketones

Annamalai Senthilvelan, Ming Tsung Tsai, Kai Chi Chang, Wen-Sheng Chung^*

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Mo(CO)₆-mediated ring opening reactions of calix[4]arene isoxazolines/isoxazoles provide a new synthetic methodology for calix[4]arenes carrying bifunctional β-hydroxy ketones or α,β-unsaturated-β-amino ketones. Mo(CO)₆ is a highly selective and convenient reagent for the ring opening process of these supramolecular isoxazolines/isoxazoles.

Original language	English
Pages (from-to)	9077-9081
Number of pages	5
Journal	Tetrahedron Letters
Volume	47
Issue number	51
DOIs	https://doi.org/10.1016/j.tetlet.2006.10.082
State	Published - 18 Dec 2006

Keywords

α,β-Unsaturated-β-amino ketones
β-Hydroxy ketones
Calix[4]arene isoxazolines/isoxazoles
Molybdenum hexacarbonyl

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title = "Mo(CO)6-mediated synthesis of calix[4]arenes carrying β-hydroxy ketones or α,β-unsaturated-β-amino ketones",

abstract = "Mo(CO)6-mediated ring opening reactions of calix[4]arene isoxazolines/isoxazoles provide a new synthetic methodology for calix[4]arenes carrying bifunctional β-hydroxy ketones or α,β-unsaturated-β-amino ketones. Mo(CO)6 is a highly selective and convenient reagent for the ring opening process of these supramolecular isoxazolines/isoxazoles.",

keywords = "α,β-Unsaturated-β-amino ketones, β-Hydroxy ketones, Calix[4]arene isoxazolines/isoxazoles, Molybdenum hexacarbonyl",

author = "Annamalai Senthilvelan and Tsai, {Ming Tsung} and Chang, {Kai Chi} and Wen-Sheng Chung",

year = "2006",

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doi = "10.1016/j.tetlet.2006.10.082",

language = "English",

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journal = "Tetrahedron Letters",

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T1 - Mo(CO)6-mediated synthesis of calix[4]arenes carrying β-hydroxy ketones or α,β-unsaturated-β-amino ketones

AU - Senthilvelan, Annamalai

AU - Tsai, Ming Tsung

AU - Chang, Kai Chi

AU - Chung, Wen-Sheng

PY - 2006/12/18

Y1 - 2006/12/18

N2 - Mo(CO)6-mediated ring opening reactions of calix[4]arene isoxazolines/isoxazoles provide a new synthetic methodology for calix[4]arenes carrying bifunctional β-hydroxy ketones or α,β-unsaturated-β-amino ketones. Mo(CO)6 is a highly selective and convenient reagent for the ring opening process of these supramolecular isoxazolines/isoxazoles.

AB - Mo(CO)6-mediated ring opening reactions of calix[4]arene isoxazolines/isoxazoles provide a new synthetic methodology for calix[4]arenes carrying bifunctional β-hydroxy ketones or α,β-unsaturated-β-amino ketones. Mo(CO)6 is a highly selective and convenient reagent for the ring opening process of these supramolecular isoxazolines/isoxazoles.

KW - α,β-Unsaturated-β-amino ketones

KW - β-Hydroxy ketones

KW - Calix[4]arene isoxazolines/isoxazoles

KW - Molybdenum hexacarbonyl

UR - http://www.scopus.com/inward/record.url?scp=33750950888&partnerID=8YFLogxK

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DO - 10.1016/j.tetlet.2006.10.082

M3 - Article

AN - SCOPUS:33750950888

VL - 47

SP - 9077

EP - 9081

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 51

ER -

Mo(CO)6-mediated synthesis of calix[4]arenes carrying β-hydroxy ketones or α,β-unsaturated-β-amino ketones

Abstract

Keywords

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