Microflow photo-radical chlorination of cycloalkanes

Hiroshi Matsubara; Yoshiko Hino; Masashi Tokizane; Ilhyong Ryu

doi:10.1016/j.cej.2010.08.086

Microflow photo-radical chlorination of cycloalkanes

Hiroshi Matsubara, Yoshiko Hino, Masashi Tokizane, Ilhyong Ryu^*

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

Photo-initiated radical chlorination of cycloalkanes was investigated using microflow reactors. Under natural light, microflow chlorination of cyclohexane with molecular chlorine proceeded well to give chlorocyclohexane with high selectivity for single-chlorination. Single-chlorination reaction of cycloalkanes with sulfuryl chloride can also be successfully carried out using a microflow reactor under irradiation using a 15. W black light.

Original language	English
Pages (from-to)	567-571
Number of pages	5
Journal	Chemical Engineering Journal
Volume	167
Issue number	2-3
DOIs	https://doi.org/10.1016/j.cej.2010.08.086
State	Published - 1 Mar 2011

Keywords

Microreactor
Molecular chlorine
Photoreaction
Radical chlorination
Sulfuryl chloride

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title = "Microflow photo-radical chlorination of cycloalkanes",

abstract = "Photo-initiated radical chlorination of cycloalkanes was investigated using microflow reactors. Under natural light, microflow chlorination of cyclohexane with molecular chlorine proceeded well to give chlorocyclohexane with high selectivity for single-chlorination. Single-chlorination reaction of cycloalkanes with sulfuryl chloride can also be successfully carried out using a microflow reactor under irradiation using a 15. W black light.",

keywords = "Microreactor, Molecular chlorine, Photoreaction, Radical chlorination, Sulfuryl chloride",

author = "Hiroshi Matsubara and Yoshiko Hino and Masashi Tokizane and Ilhyong Ryu",

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AU - Matsubara, Hiroshi

AU - Hino, Yoshiko

AU - Tokizane, Masashi

AU - Ryu, Ilhyong

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Y1 - 2011/3/1

N2 - Photo-initiated radical chlorination of cycloalkanes was investigated using microflow reactors. Under natural light, microflow chlorination of cyclohexane with molecular chlorine proceeded well to give chlorocyclohexane with high selectivity for single-chlorination. Single-chlorination reaction of cycloalkanes with sulfuryl chloride can also be successfully carried out using a microflow reactor under irradiation using a 15. W black light.

AB - Photo-initiated radical chlorination of cycloalkanes was investigated using microflow reactors. Under natural light, microflow chlorination of cyclohexane with molecular chlorine proceeded well to give chlorocyclohexane with high selectivity for single-chlorination. Single-chlorination reaction of cycloalkanes with sulfuryl chloride can also be successfully carried out using a microflow reactor under irradiation using a 15. W black light.

KW - Microreactor

KW - Molecular chlorine

KW - Photoreaction

KW - Radical chlorination

KW - Sulfuryl chloride

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M3 - Article

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JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

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ER -

Microflow photo-radical chlorination of cycloalkanes

Abstract

Keywords

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