Metal catalyst-free by design. the synthesis of amides from alkyl iodides, carbon monoxide and amines by a hybrid radical/ionic reaction

Ilhyong Ryu; Kiyoto Nagahara; Nobuaki Kambe; Noboru Sonoda; Sergio Kreimerman; Mitsuo Komatsu

doi:10.1039/a805815f

Metal catalyst-free by design. the synthesis of amides from alkyl iodides, carbon monoxide and amines by a hybrid radical/ionic reaction

Ilhyong Ryu^*, Kiyoto Nagahara, Nobuaki Kambe, Noboru Sonoda, Sergio Kreimerman, Mitsuo Komatsu

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

Amides can be synthesized from alkyl iodides and amines in the presence of CO (20-25 atm), without using transition metal catalyst; the radical cascade is initiated thermally using AIBN and allyltributyltin.

Original language	English
Pages (from-to)	1953-1954
Number of pages	2
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/a805815f
State	Published - 21 Sep 1998

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title = "Metal catalyst-free by design. the synthesis of amides from alkyl iodides, carbon monoxide and amines by a hybrid radical/ionic reaction",

abstract = "Amides can be synthesized from alkyl iodides and amines in the presence of CO (20-25 atm), without using transition metal catalyst; the radical cascade is initiated thermally using AIBN and allyltributyltin.",

author = "Ilhyong Ryu and Kiyoto Nagahara and Nobuaki Kambe and Noboru Sonoda and Sergio Kreimerman and Mitsuo Komatsu",

year = "1998",

month = sep,

day = "21",

doi = "10.1039/a805815f",

language = "English",

pages = "1953--1954",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "18",

}

Metal catalyst-free by design. the synthesis of amides from alkyl iodides, carbon monoxide and amines by a hybrid radical/ionic reaction. / Ryu, Ilhyong; Nagahara, Kiyoto; Kambe, Nobuaki; Sonoda, Noboru; Kreimerman, Sergio; Komatsu, Mitsuo.

In: Chemical Communications, No. 18, 21.09.1998, p. 1953-1954.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Metal catalyst-free by design. the synthesis of amides from alkyl iodides, carbon monoxide and amines by a hybrid radical/ionic reaction

AU - Ryu, Ilhyong

AU - Nagahara, Kiyoto

AU - Kambe, Nobuaki

AU - Sonoda, Noboru

AU - Kreimerman, Sergio

AU - Komatsu, Mitsuo

PY - 1998/9/21

Y1 - 1998/9/21

N2 - Amides can be synthesized from alkyl iodides and amines in the presence of CO (20-25 atm), without using transition metal catalyst; the radical cascade is initiated thermally using AIBN and allyltributyltin.

AB - Amides can be synthesized from alkyl iodides and amines in the presence of CO (20-25 atm), without using transition metal catalyst; the radical cascade is initiated thermally using AIBN and allyltributyltin.

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U2 - 10.1039/a805815f

DO - 10.1039/a805815f

M3 - Article

AN - SCOPUS:0002629226

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EP - 1954

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

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ER -