Luminescent properties and energy transfer of green-emitting Ca3 Y2(Si3O9)2: Ce3+, Tb3+phosphor

Yi Chen Chiu*, Wei Ren Liu, Yao Tsung Yeh, Shyue Ming Jang, Teng-Ming Chen

*Corresponding author for this work

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66 Scopus citations

Abstract

Green-emitting phosphors of Ca3 Y2(Si3 O 9)2: Ce3+, Tb3+ have been synthesized by solid-state reaction. The luminescence properties were characterized by photoluminescence (PL) and photoluminescence excitation spectra, reflection spectra, and a detection system using an integrating sphere equipped with a spectrofluorometer. With Ce3+ co-doping as a sensitizer, the PL intensity of Ca3 Y2(Si3 O9)2: Ce3+, Tb3+was found to increase dramatically by a factor of 5.8. For comparison, the emission intensity of composition-optimized Ca3 Y2(Si3 O 9)2: Ce3+, Tb3+is 126% of green commodity, ZnS:Cu,Al. The quantum efficiency of Ca3 Y 2(Si3 O9)2: Ce3+, Tb 3+is as high as 77% compared to ZnS:Cu,Al (53%). The energy transfer from Ce3+to Tb3+is also of resonant type via a dipole-dipole mechanism with the energy-transfer critical distance of 6.78 Å. By utilizing the principle of energy transfer and appropriate tuning of activator contents, we are currently evaluating the potential application of Ca3 Y2(Si3 O9)2: Ce 3+, Tb3+as a highly efficient UV-convertible phosphor.

Original languageEnglish
JournalJournal of the Electrochemical Society
Volume156
Issue number8
DOIs
StatePublished - 22 Jul 2009

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